\1 refers to the first capturing group.
\2 refers to the second capturing group.
\2 refers to the third capturing group.
. . .

Let’s understand more clearly with an example.
Suppose we have a strong
Hello World 123 Hello World Hello 123
The regular expression to match this string is :

(Hello)\s(World)\s(123)\s\1\s\2\s\1\s\3

Explanation :
(Hello) : Hello inside these two parentheses acts as a group.
\s : Represents space here.
(World) : World inside these two parentheses acts as a group.
(123) : 123 inside these two parentheses acts as a group.
\1 : Refers 1st capturing group which is Hello here
\2 : Refers 2nd capturing group which is World here
\3 : Refers 3rd capturing group which is 123 here

Remember: Here \1,\2 or \3 is the reference of capturing group but does not act as capturing group. That means in the regular expression (Hello)\s(World)\s(123)\s\1\s\2\s\1\s\3 , the highlighted \1 and \2 will not be 4th and 5th capturing groups.